By K H Overton
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Prior to now fifteen years there was a dramatic bring up within the variety of diversified surfaces whose buildings were made up our minds experimentally. for instance, while in 1979 there have been purely 25 recorded adsorption constructions, to this point there are greater than 250. This quantity is for that reason a well timed assessment of the state of the art during this dynamic box.
This booklet is pretty well to the purpose, with no placing every thing into riddles and beating round the bush to confuse you.
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M. Sathe, and A. S. Rao, Chem. , 1969,921. l E 7M. Santelli and M. Bertrand, Bull. chim. France, 1973, 2326; B. Ragonnet, M. Santelli, and M. , p. 3119. C. H. Brieskorn and H. H. Frohlich, Arch. , 1973, 306, 641. 19’ V. V. Bazyl’chik, I. I. Bardyshev, N. M. Ryabushkina, N . P. Polyakova, and P. I. Fedorov, Vestsi Akad. Navuk Belarusk. S . S . R . , Ser. khim. Navuk, 1973, 104. J. Ficini and A. M. Touzin, Tetrahedron Letters, 1974, 1447. ' 94 Some transformations of P-pyronene (146), available from pyrolysis of a-pinene, are described (Scheme 14),in the course of which dehydro-1,4-cineol(l48) is quoted [the analogous oxide (149) HO R = (147) R = (146) Reagents: i, hv, O,-sensitizer; ii, LiAlH,; iii, HCrO, (two-phase); iv, NaBH,; vi, monoperphthalic acid.
Udarov, Zhur. org. , 1973,9, 1670. I. I. Bardyshev and E. F. Buinova, Vestsi Akad. Naouk Befarusk. , Ser. khim. Naouk, 1974, 94 (Chem. , 1973,79, 105 422). B. A. Arbuzov, Z. G. Isaeva, and V. A. Shaikhutdinov, Doklady Akad. , 1973, 210, 837; B. A. Arbuzov, Z. G. Isaeva, and E. Kh. Kazakova, Imest. Akad. Nauk S . S . S . R . , Ser. , 1973, 2554; Doklady Akad. , 1974, 215, 113 (see Vol. 4, p. 64). B. A. Arbuzov, Z. G. Isaeva, R. R. D'yakonova, and G. A. Bakaleinik, Izvest. Akad. , Ser. , 1973, 2543, 2549 (see Vol.
288 Rapid introduction to the 3,7,7-trimethylnorpinane series is by direct reduction of the hydroxymethylene derivative (224; R = 282 283 284 285 186 287 288 B. B. Snider, J . Org. , 1974,39,255; cJ J. Matsubara, T. Kishimoto, H. Yamamoto, and W. Minematsu, Nippon Kagaku Kaishi, 1972, 669. M. M. Chatzopoulos and J. P. Montheard, Actual. , 1974, No. 5 , p. 56; CJ Vol. 1 , p. 46. From R. D. Sands, Synth. , 1973,3, 81; such a reaction might appear possible, but the Reporter has found Sands’s work to be erroneous.