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By K L Mittal; Robert D Vold; Marjorie J Vold; American Chemical Society. Division of Colloid and Surface Chemistry.; American Chemical Society. Meeting (ed.)

Refereed and edited papers at the most present advancements within the idea and functions of curves and surfaces Thermodynamics of adsorption and interparticle forces / D.H. Everett and C.J. Radke -- Configurational habit of remoted chain molecules adsorbed from athermal recommendations / M. Lal, M.A. Turpin, K.A. Richardson, and D. Spencer -- Equilibrium movie strain on a flat, low-energy strong / Robert J. reliable -- Binding of solute and solvent on the interface and the gibbs floor extra / D.K. Chattoraj and S.P. Moulik -- Mechanism of sulfonate adsorption on the silver iodide-solution interface / okay. Osseo-Asare, D.W. Fuerstenau, and R.H. Ottewill -- Adsorption of dyes on water-swollen and non-swelling good substrates / S.R. Sivaraja Iyer, A.S. Chanekar, and G. Srinivasan -- Adsorption of polystyrene on graphon from toluene / Victor okay. Dunn and Robert D. Vold -- Adsorption of ionic surfactants to porous glass : the exclusion of micelles and different solutes from adsorbed layers and the matter of adsorption maxima / Pasupati Mukerjee and Aroonsri Anavil -- DTA research of water in porous glass / Chaur-Sun Ling and W. Drost-Hansen -- Monolayer stories. five, Styrene-acrylic acid motion pictures on aqueous substrates / Erwin Sheppard and Noubar Tcheurekdjian -- interplay of calcium ions with the combined monolayers of stearic acid and stearyl alcohol at pH 8.8 / D.O. Shah -- touch angles in Newton-Black cleaning soap motion pictures drawn from options containing sodium dodecyl sulphate and electrolyte / J.A. De Feijter and A. Vrij -- Stratification in unfastened liquid movies / J.W. Keuskamp and J. Lyklema -- floor chemical homes of hugely fluorinated polymers / Marianne ok. Bernett and W.A. Zisman -- impact of floor oxygen complexes on floor habit of carbons / Balwant Rai Puri -- floor houses of nickel hydroxide sooner than and after dehydration to nickel oxide / M. subject, F.J. Micale, C.L. Cronan, H. Leidheiser, Jr., and A.C. Zettlemoyer -- The size of low interfacial rigidity through the spinning drop strategy / J.L. Cayias, R.S. Schechter, and W.H. Wade -- Adhesion of ice frozen from dilute electrolyte strategies / H.H.G. Jellinek -- Mechanism of olfaction defined utilizing interfacial stress measurements / D. V. Rathnamma -- position of double interactions and spreading strain in particulate soil elimination / Hermann Lange

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Extra info for Adsorption at interfaces : papers from a symposium honoring Robert D. Vold and Marjorie J. Vold sponsored by the Division of Colloid and Surface Chemistry at the 167th meeting of the American Chemical Society, Los Angeles, Calif., April 2-5, 1974

Example text

134 Ε. J. Arlman and P. Cossee, / . Catalysis, 3 (1964) 80, 89, 99. 398 TITANIUM: R. J. H. CLARK arrangement in which the monomer molecule is inserted between the existing chain and the transition metal atom X—Μ— K—U— A + C2H4 X —— Μ— ΜI I— — — X—Μ M- A A CH2 / R \ -CH2 ^ X The latter still has a vacant position for further attachment of an olefin molecule. It is believed that the rearrangement of the alkyl group is the rate-determining step and that the alkyl aluminium is not essential for the propagation step.

The aluminium-containing compound mentioned above, which covers the faces parallel to [001], does not appear to be catalytically active; these faces are estimated to constitute 9 5 % of the total surface of a-TiC^. On the other hand, certain Ti-Al bimetallic complexes (such as those synthesized by Natta and coworkers) d o function as catalysts in solution. Indeed, it seems beyond doubt that both Arlman-Cossee centres (see below) and bimetalhc centres do in general act as catalyst centres. Extensive work by Boor and coworkers^^^ has further defined the nature and distribution of stereospecific and non-stereospecific polymerization sites in the TÍCI3 lattice.

Sinn, Angew. Chem. 70 (1958) 496; Naturwissenschaften, 45 (1958) 312. 134 Ε. J. Arlman and P. Cossee, / . Catalysis, 3 (1964) 80, 89, 99. 398 TITANIUM: R. J. H. CLARK arrangement in which the monomer molecule is inserted between the existing chain and the transition metal atom X—Μ— K—U— A + C2H4 X —— Μ— ΜI I— — — X—Μ M- A A CH2 / R \ -CH2 ^ X The latter still has a vacant position for further attachment of an olefin molecule. It is believed that the rearrangement of the alkyl group is the rate-determining step and that the alkyl aluminium is not essential for the propagation step.

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