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Lachmann, and G. Muller, Ornanometallies, 1990, 2, 190; (b) W. Moene, M. M. T. de Kanter. W. L. , 1990, 3l, 2641. 20(a) J. Barluenga, Pure ADD^. J. E. Galle, J. Ora. , 1990, 55, 4835. 21 M. P. W. Klumpp, Recl. Trav. , 1990, 109. 305. 22. P. J. K. Lee, J. Am. Chem. , 1990, 112, 1629. 23. D. M. H. Harrison, R. Lagow, H. E. Cox, J. Am. Chem. , 1990, 112, 2455. B. S. Akkerman, and F. Bickelhaupt, Organometallics, 24. 1990, 2, 2893. l(a) u, w.. , Group 1: The Alkali and Coinage Metals 11 25(a) T. -I.

43. 44. 45. 46. 47. 48. 49. 50. 51. , I,1990, 52. 53. 54. 55. 56. 57. 58. 59. 757. R. Norris, A. L. Beauchamp, J. Crystalloar. Spectrosc. , 1990, 20, 23. G. S. Gimeno, A. S. E. Castel,lano, J. Oruanomet. , 1990, 384, 19. G. S. Gimeno, A. S. Casas and J. Sordo, JOraanomet. , 1990, 3 9 0 , 293. K. K. M. Roundhill, Polvhedron 1990, 9, 597. H. Block, M. Brito, M. Gernon, D. McGowty, H. Kang and J. Zubieta, Inors. 1990, 29, 3172. P. Dufour, Y. Dartiguenave, M. Dartiguenave, N. -M. Lebuis, F. L. Beauchamp, Can.

R*Tl. Oxygen inserts into the R-Mg (10) can be converted to R*MgOR on treatment Compounds (9) have been obtained from reactions of R2Mg and (M = Na or K) NMR epectra suggest that the interactions of R2Mg with R ' O M provide" magnesiate species, 2M' [R2Mg(fi-0R')2MgR2l2-; groups at Bus aided the structural elucidation. g. added. the reduction ROM or R4NX, is Reactions of pyridazine with Griqnard reagents proceed via homolytic mechanisms. l3 3 Calcium, strontium and barium Highly reactive metal ( M ) powders are obtained by reduction of MI2 by either (a) potassium in THF (for M = Ca, Sr or Ba) or (b) PhPh-' , Li'.

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