By Ivon Flament
This, the 1st accomplished assessment of espresso style chemistry is fullyyt devoted to taste parts and offers the significance of analytical thoughts for the standard regulate of harvesting, roasting, conditioning and distribution of meals.
* offers a reference for espresso experts and an advent to style chemistry for non-specialists
* the writer is a study chemist with Firmenich SA, one of many few nice style and perfume businesses on this planet
* comprises the newest references (up to 2001) for the identity of eco-friendly and roasted espresso aroma volatiles
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M. Sathe, and A. S. Rao, Chem. , 1969,921. l E 7M. Santelli and M. Bertrand, Bull. chim. France, 1973, 2326; B. Ragonnet, M. Santelli, and M. , p. 3119. C. H. Brieskorn and H. H. Frohlich, Arch. , 1973, 306, 641. 19’ V. V. Bazyl’chik, I. I. Bardyshev, N. M. Ryabushkina, N . P. Polyakova, and P. I. Fedorov, Vestsi Akad. Navuk Belarusk. S . S . R . , Ser. khim. Navuk, 1973, 104. J. Ficini and A. M. Touzin, Tetrahedron Letters, 1974, 1447. ' 94 Some transformations of P-pyronene (146), available from pyrolysis of a-pinene, are described (Scheme 14),in the course of which dehydro-1,4-cineol(l48) is quoted [the analogous oxide (149) HO R = (147) R = (146) Reagents: i, hv, O,-sensitizer; ii, LiAlH,; iii, HCrO, (two-phase); iv, NaBH,; vi, monoperphthalic acid.
Udarov, Zhur. org. , 1973,9, 1670. I. I. Bardyshev and E. F. Buinova, Vestsi Akad. Naouk Befarusk. , Ser. khim. Naouk, 1974, 94 (Chem. , 1973,79, 105 422). B. A. Arbuzov, Z. G. Isaeva, and V. A. Shaikhutdinov, Doklady Akad. , 1973, 210, 837; B. A. Arbuzov, Z. G. Isaeva, and E. Kh. Kazakova, Imest. Akad. Nauk S . S . S . R . , Ser. , 1973, 2554; Doklady Akad. , 1974, 215, 113 (see Vol. 4, p. 64). B. A. Arbuzov, Z. G. Isaeva, R. R. D'yakonova, and G. A. Bakaleinik, Izvest. Akad. , Ser. , 1973, 2543, 2549 (see Vol.
288 Rapid introduction to the 3,7,7-trimethylnorpinane series is by direct reduction of the hydroxymethylene derivative (224; R = 282 283 284 285 186 287 288 B. B. Snider, J . Org. , 1974,39,255; cJ J. Matsubara, T. Kishimoto, H. Yamamoto, and W. Minematsu, Nippon Kagaku Kaishi, 1972, 669. M. M. Chatzopoulos and J. P. Montheard, Actual. , 1974, No. 5 , p. 56; CJ Vol. 1 , p. 46. From R. D. Sands, Synth. , 1973,3, 81; such a reaction might appear possible, but the Reporter has found Sands’s work to be erroneous.