By Hari Singh Nalwa, Foreword by Richard E. Smalley
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Additional info for Encyclopedia of Nanoscience and Nanotechnology Volume 9
The performances of these sensors have been measured with respect to model volatile compounds of interest for practical applications. While the sensitivities showed by these sensors were higher compared to the corresponding casting coated sensors, the presence of a single layer of the sensing material induced a saturation of the speciﬁc sites at very low concentration of the analytes. In Figure 18 the sensitivities of these sensors toward different VOCs have been reported. Very recently, a chemisorbed chiral porphyrin diad (Fig.
This is the ﬁrst approach to develop a complete artiﬁcial sensorial system. More recently CMEs were fabricated by the electropolymerization of different metal complexes of TMHPP on glassy carbon electrodes, using the cyclic voltammetric method . The resulting electrodes were used as potentiometric sensors and demonstrated higher resolution and stability than the corresponding PVC based electrodes. These CMEs were assembled in an array conﬁguration and utilized to analyze several samples. In particular, this array was able to discriminate compounds, each one used as a model of the ﬁve classical tastes.
A similar comparison was carried out for the analysis of UHT milk samples . In this test, 13 different commercially available brands of Porphyrin-Based Chemical Sensors UHT milk were taken into consideration. Each of them was analyzed with the electronic nose, while the panel searched the presence and the intensity of a speciﬁc sensation, which is a drawback for this particular product: the aroma of burned milk. There was perfect agreement between sensorial analysis and electronic nose results and this was surprising because sensorial analysis was aimed at evaluating only one of the aroma features, while the electronic nose data were related to the whole aroma composition.