Download N-Heterocyclic Carbenes in Transition Metal Catalysis by Frank Glorius PDF

By Frank Glorius

It used to be in basic terms within the early Nineteen Nineties that carbenes with the carbene carbon being included in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) have been came across to be solid sufficient to be remoted. because the first file at the program of NHCs as ligands in transition steel catalysis in 1995, NHC have chanced on a variety of functions and feature been demonstrated as a flexible and necessary classification of ligands. for lots of reactions like metathesis or cross-coupling reactions NHCs have usually develop into the ligands of selection, permitting in a different way tough variations. during this publication major specialists have surveyed significant components of program of NHC steel complexes in catalysis. The authors have positioned a different specialise in nickel- and palladium-catalyzed reactions, on purposes in metathesis reactions, on oxidation reactions and at the use of chiral NHC-based catalysts. This compilation is rounded out through an introductory bankruptcy and a bankruptcy facing man made routes to NHC steel complexes. using NHC as ligands in catalysis has reached a definite point of adulthood and this e-book permits the reader to get a balanced view of this more and more very important ligand classification.

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Extra resources for N-Heterocyclic Carbenes in Transition Metal Catalysis (Topics in Organometallic Chemistry, Volume 21)

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52 52 53 53 54 57 58 59 59 60 61 63 63 64 65 5 Dehalogenation Reactions . . . . . . . . . . . . . . 3 Transformations Through C–H Activation Oxidation of Methane to Methanol . . Direct Arylation Reactions . . . . . Hydroarylation of Alkynes . . . . . . . 66 66 67 68 7 Cyclization of Enynes . . . . . . . . . . . . . . . 69 8 Hydrogenation Reactions . . . . . . . . . . . . . . 2 Oxidation Reactions . . . . . . . . . .

3 Transformations Through C–H Activation Oxidation of Methane to Methanol . . Direct Arylation Reactions . . . . . Hydroarylation of Alkynes . . . . . . . 66 66 67 68 7 Cyclization of Enynes . . . . . . . . . . . . . . . 69 8 Hydrogenation Reactions . . . . . . . . . . . . . . 2 Oxidation Reactions . . . . . . . . . . . . . . . Oxidation of Alcohols . . . . . . . . . . . . . . . Wacker Oxidation and Related Transformations .

Navarro O, Nolan SP (2006) Synthesis, 366 108. O’Brien CJ, Kantchev EAB, Valente C, Hadei N, Chass GA, Lough A, Hopkinson AC, Organ MG (2006) Chem Eur J 12:4743 109. Organ MG, Avola S, Dubovyk I, Hadei N, Kantchev EAB, O’Brien CJ, Valente C (2006) Chem Eur J 12:4749 110. Boydston AJ, Williams KA, Bielawaski CW (2005) J Am Chem Soc 127:12496 111. Muelhofer M, Strassner T, Herrmann WA (2002) Angew Chem Int Ed 41:1745 112. Kernbach U, Ramm M, Luger P, Fehlhammer WP (1996) Angew Chem Int Ed Engl 35:310 113.

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